Product ID:IODINE SOLUTION
MSDS Date:03/02/1989
FSC:6810
NIIN:01-021-0355
MSDS Number: BSRBZ

CITY CHEMICAL CORP

132 WEST 22ND ST
NEW YORK, NY 10011
US

Emergency Phone: 212-929-2723;201-653-6900

Info Phone: 212-929-2723;201-653-6900

Preparer: PETER WOLPERT

Cage: 83628

CITY CHEMICAL CORPORATION

JERSEY CITY, NJ 07310 US

Telephone: 201-653-6900/800-248-2436

Cage: 83628

IODINE

CAS: 7553-56-2

RTECS: NN1575000

Fraction By Weight: 3%

OSHA PEL 0.1 PPM, C

ACGIH TLV: 0.1 PPM, C

POTASSIUM IODIDE

CAS: 7681-11-0

RTECS: TT2975000

Fraction By Weight: 20-50%

DISTILLED WATER

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: TO 100%

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:HARMFUL IF SWALLOWED, INHALED, OR
ABSORBED THROUGH SKIN. MATERIAL IS EXTREMELY DESTRUCTIVE TO TISSUE
OF MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT, EYES AND SKIN.
SYMPTOMS OF EXPOSURE MAY INCLUDE BU RNING SENSATION, COUGHING,
WHEEZING, LARYNGITIS, SHORTNESS OF BREATH, HEADACHE, NAUSEA AND
VOMITING. (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HEALTH HAZARDS: EXPOSURE CAN CAUSE STOMACH
PAINS, VOMITING AND DIARRHEA, SKIN EXPOSURE MAY CAUSE STAINS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING GIVE
ARTIFICIAL RESPIRATION PREFERABLY MOUTH-TO-MOUTH. IF BREATHING IS
DIFFICULT GIVE OXYGEN. CALL PHYSICIAN. INGESTION: GIVE WATER TO
DRINK AND GET M EDICAL ATTENTION. SKIN: WASH WITH SOAP AND WATER.
GET MEDICAL ADVICE IF IRRITATION DEVELOPS. EYE: IMMEDIATELY FLUSH
WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. CALL PHYSICIAN IF
IRRITATION DEVELOPS.

Extinguishing Media:NOT CONSIDERED TO BE A FIRE HAZARD. USE ANY MEANS
SUITABLE FOR EXTINGUISHING SURROUNDING FIRE.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:WHEN HEATED TO DECOMPOSITION, IT MAY EMIT
TOXIC FUMES OF IODINE, AND IODINE COMPOUNDS WHICH MAY REACT WITH
REDUCING MATERIAL.

Spill Release Procedures:VENT AREA OF SPILL OR LEAK. WEAR NIOSH/MSHA
APPROVED SCBA, RUBBER BOOTS, AND HEAVY RUBBER GLOVES. ABSORB LIQ
SPILLS WITH DRY ABSORBENT. CONTAINERIZE UNUSABLE MATL FOR DISP IN
AN APPROVED WASTE FACILIT Y. WASH SPILL SITE AFTER MAL PICK-UP
ISCOMPLETE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN COOL, DRY VENTILATED AREA.
PROTECT FROM PHYSICAL DAMAGE. PROTECT FROM FREEZING.
Other Precautions:NONE INDICATED.

Respiratory Protection:NIOSH/MSHA APPROVED DUST/MIST RESPIRATOR. UNDER
NORMAL CONDITIONS RESPIRATORY PROTECTION NOT REQUIRED.
Ventilation:USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION.
Protective Gloves:RUBBER OR PLASTIC GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS (SUPDAT)
Other Protective Equipment:SAFETY SHOWER AND EYEWASH BATH.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER. EYE PROT: GOGGLES AND FULL LENGTH
FACESHIELD .

Boiling Pt:B.P. Text:212F,100C
Solubility in Water:INFINITELY MISCIBLE
Appearance and Odor:REDDISH-BROWN LIQUID, SLIGHT IODINE ODOR.

Stability Indicator/Materials to Avoid:YES
(AS IODINE) MAGNESIUM, ZINC, AMMONIA, ALUMINUM, ANTIMONY, REACTS
VIOLENTLY WITH ACETALDEHYDE. CORRODES STEEL.
Stability Condition to Avoid:AVOID PHYSICAL SHOCK OR DAMAGE. GLASS
AMPOULE IS VERY FRAGILE.
Hazardous Decomposition Products:WHEN HEATED TO DECOMPOSITION, IT EMITS
TOXIC FUMES OF IODINE.

Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH ALL APPLICABLE
FEDERAL, STATE, AND LOCAL ENVIRONMENTAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.